The lower octanes actually have a faster burn rate, but higher compression (or less heat efficient) engines require the higher octane to combat detonation.
Different companies use different additives and some use a mix of ethanol (? I can't remember) to help with emissions. I've never noticed enough difference between different brands to warrant a look, but there are some stations I avoid like the plague because they always seem to have a water problem. Get a little water in your tank and I guarantee you'll tell a difference. That's why I stick with the larger name-brand stations that have a lot of turnover.
Different companies use different additives and some use a mix of ethanol (? I can't remember) to help with emissions. I've never noticed enough difference between different brands to warrant a look, but there are some stations I avoid like the plague because they always seem to have a water problem. Get a little water in your tank and I guarantee you'll tell a difference. That's why I stick with the larger name-brand stations that have a lot of turnover.